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Ingredients/Compound/Mono-Ammonium Glycyrrhizinate

Mono-Ammonium Glycyrrhizinate.

Strength pending.The research strength is not set yet.

It's the water-soluble salt of licorice's sweet active. At tiny amounts it sweetens and masks bitterness. Higher intakes act on how the kidney handles cortisol, sodium and potassium.

MACompound
Mono-Ammonium GlycyrrhizinateIngredientMD
Category
Compound

What Mono-Ammonium Glycyrrhizinate is, and what it does.

Does it work
Suits liquid and powder formulas that need sweetness without sugar. It suits people who keep total licorice intake modest and who keep an eye on potassium and blood pressure.
How much to take
No dose figure is on record here. What is on record is a ceiling: several national authorities set daily glycyrrhizin guidance around 100 mg for the general population.
Time to feel it
Sweetness is immediate on the tongue, slow to arrive fully and slow to fade. The electrolyte effect builds over days to weeks and is cumulative rather than acute.
The first dose
Day one is a taste effect: sweet, lingering, unmistakably licorice. Nothing else registers, because the kidney effect needs repeated intake rather than one serving.
With regular use
Weeks of intake above the guidance level show as sodium retention, higher urinary potassium and lower plasma renin and aldosterone. Those are lab readings, not sensations.
How well tolerated
Fine at the sweetener levels used in formulation. Intake adds up across licorice sweets, teas and supplements, and people watching blood pressure or potassium should ask a clinician.
How it feels
Intensely sweet with a long licorice finish that some people love and others find cloying. Beyond taste there's no felt effect at formulation levels.
The overlooked benefit
Your gut bacteria have to clip two sugar units off before anything reaches the bloodstream, so the same amount lands quite differently in two different people.

The proof, claim by claim.

These words describe the research, not the molecule's worth. Research strength is how much work stands behind one claim, and it is never a product score.

  • sweetening and bitterness masking in formulationNarrative review
  • inhibition of 11-beta-hydroxysteroid dehydrogenase type 2 and electrolyte handlingRandomised trial
  • daily intake guidance for glycyrrhizinNarrative review
  • microbial conversion to glycyrrhetinic acid before absorptionNarrative review
  • digestive comfort from licorice preparationsNarrative review
PubMedCochraneClinicalTrials.govNIH ODSSUPP.AILabs test. IngredientMD verifies.PubMedCochraneClinicalTrials.govNIH ODSSUPP.AILabs test. IngredientMD verifies.
Pairs well with8 on file

Why these belong in the same formula. Each row says what the basis is, from settled biochemistry through to a trial that measured the pair.

Mono-Ammonium Glycyrrhizinate + PotassiumEstablished endocrine pharmacology. Glycyrrhizin and its metabolite glycyrrhetinic acid inhibit 11-beta-hydroxysteroid dehydrogenase type 2 in the kidney, leaving cortisol to act at the mineralocorticoid receptor, which drives sodium retention and urinary potassium loss.

This is the single most important interaction for the ingredient and it runs against potassium status. Sustained intake pushes potassium out in the urine, so a formula pairing the two is not a neutral combination and potassium supplementation does not cancel the underlying enzyme inhibition. Anyone taking it at meaningful daily amounts for weeks should have potassium considered rather than assumed. The effect is dose and duration dependent.

Mono-Ammonium Glycyrrhizinate + SodiumSame 11-beta-HSD2 inhibition, seen from the sodium side. Mineralocorticoid receptor activation increases renal sodium reabsorption and expands extracellular fluid volume.

Sodium retention and volume expansion raise blood pressure, and a high sodium intake stacks on top of that same mechanism. The two work in the same direction rather than opposing each other. This is the reason regulatory bodies in several countries cap daily glycyrrhizin intake from confectionery and supplements.

Mono-Ammonium Glycyrrhizinate + Licorice rootGlycyrrhizin is the principal saponin of Glycyrrhiza glabra, and the mono-ammonium salt is that same molecule isolated and salified.

Combining the salt with whole licorice root stacks the same active from two sources and the total daily glycyrrhizin is what matters for the electrolyte effect. Formulators sometimes miss this because the label lists two apparently different ingredients. Deglycyrrhizinated licorice is the exception, since the active has been removed from it.

Mono-Ammonium Glycyrrhizinate + Marshmallow rootTraditional pairing in demulcent throat and gastric formulas, based on mucilage polysaccharides rather than any shared mechanism with glycyrrhizin.

Marshmallow contributes viscous mucilage that coats mucosal surfaces, a physical effect quite separate from anything glycyrrhizin does. The combination is long-standing in herbal practice. No controlled work has tested whether the pair does more than either alone.

Mono-Ammonium Glycyrrhizinate + Slippery elmSame demulcent formulation convention, mucilage plus glycyrrhizin in soothing preparations.

Slippery elm bark supplies polysaccharide mucilage with a physical coating action. The pairing is formulation practice with a long history and no trial evidence for the combination specifically. It carries the same electrolyte considerations as glycyrrhizin alone.

Mono-Ammonium Glycyrrhizinate + GlycineEstablished formulation chemistry. Glycine is used as a buffering and taste-modifying agent alongside glycyrrhizinate salts, which are intensely sweet and carry a lingering aftertaste.

Glycyrrhizinate salts are used at low levels as sweeteners and flavour maskers in oral products. Glycine softens the residual bitterness and licorice note. This is sensory formulation and has no bearing on the physiological effects of either ingredient.

Mono-Ammonium Glycyrrhizinate + Milk thistle silymarinCo-formulation convention in hepatic-support products across East Asia and Europe, where glycyrrhizin preparations and silymarin are frequently combined.

Both are used in formulas aimed at elevated liver enzymes and both have antioxidant and membrane-related mechanistic work behind them. The combination is common commercially. Controlled comparisons of the pair against either alone are thin, so read the pairing as convention supported by mechanism rather than as a demonstrated additive effect.

Mono-Ammonium Glycyrrhizinate + Vitamin CFormulation antioxidant practice in aqueous products containing the glycyrrhizinate salt.

Ascorbate is added to aqueous formulas to protect oxidisable co-ingredients and hold pH in a range where the glycyrrhizinate salt stays dissolved. It is an excipient-level relationship. No physiological interaction between the two has been described.

Who should be cautious

Nothing specific on file for Mono-Ammonium Glycyrrhizinate. Match the label to the daily amount above, and tell your doctor what you take.

Not medical advice. Show the label to your pharmacist.

What Mono-Ammonium Glycyrrhizinate actually does.

Established

It blocks the kidney enzyme that switches off cortisol locally. Cortisol then acts like a salt-retaining hormone, so you hold sodium and lose potassium.

Established

Your gut bacteria have to cut the sugars off before the active form is absorbed. That step differs from person to person.

Established

The free acid barely dissolves. Turning it into an ammonium salt makes it water-soluble enough to put in a liquid.

Established

It is intensely sweet with a lingering finish, so tiny amounts are used just to cover bitter tastes.

Grown, 6 steps on record

Where Mono-Ammonium Glycyrrhizinate comes from.

It starts as licorice root. Extract the root in hot water, drop the active out with acid, clean it up, then react it with ammonia so it dissolves properly. What you get is a very sweet white powder that is chemically the same active found in licorice.

Made from a plant. What ends up in the capsule tracks the harvest, so batch testing and a stated marker matter more here than with a made molecule.

Starts as
Licorice root (Glycyrrhiza glabra, uralensis or inflata)

Cultivated and wild-harvested roots and stolons, mainly from China, Uzbekistan, Turkey, Iran and Afghanistan. Glycyrrhizin content in dried root typically runs a few percent by weight and varies by species and growing region.

Extracted by
Hot water or dilute alkaline extraction

The root is extracted to pull glycyrrhizin, present in the plant as calcium and potassium salts, into solution along with flavonoids and polysaccharides.

Purified by
Acid precipitation and recrystallisation

Acidifying the extract precipitates glycyrrhizic acid, which is filtered, washed and recrystallised to raise purity.

Converted by
Neutralisation with ammonia

The purified acid is reacted with ammonia to form the mono-ammonium salt, which converts a poorly soluble acid into a water-soluble article.

Standardised to
Assay to glycyrrhizin content

Finished material is assayed by HPLC against a glycyrrhizin reference, commonly to 98 percent or higher for the salt.

Ends up as
Crystalline powder

Sold as a white to pale yellow crystalline powder for oral, topical and food applications.

Getting Mono-Ammonium Glycyrrhizinate from food.

The whole-food sources on file. A supplement closes the gap, it does not replace dinner.

Dried licorice rootLicorice confectioneryLicorice herbal tea

A gram-for-gram figure (how much of each you would eat to match a dose) will appear here once it is sourced and reviewed. This page will not print a number it cannot cite.

The forms it comes in.

Single ammonium saltOne ammonium counterion on the glycyrrhizic acid backbone, water-soluble at neutral pHFits Aqueous oral liquids, topical formulations and flavour-masking applicationsTrade-off Solubility falls off as pH drops toward acid, and the ammonium counterion contributes nothing beyond dissolutionActive and formulation aid
Double ammonium saltBoth carboxyl groups neutralised, giving higher aqueous solubility than the mono saltFits Injectable and high-concentration liquid preparations used in East Asian clinical practiceTrade-off Raises the ammonium load per gram, and the higher solubility is only useful where concentration is the constraint
Potassium saltPotassium counterions, highly water-soluble, the standard cosmetic-grade articleFits Topical and skincare formulations where an aqueous-soluble licorice active is wantedTrade-off Adds potassium to the formula, which matters in some electrolyte-sensitive compositionsActive and formulation aid
Stereoisomeric magnesium saltThe 18-alpha stereoisomer as a magnesium salt, a different spatial configuration from the natural 18-beta formFits Clinical preparations in China where the isomer is specified by pharmacopoeiaTrade-off The isomer difference means data on 18-beta glycyrrhizin does not transfer directly to it
Free acidUnsalified parent compound, poorly soluble in cold waterFits Dry powder blends and extracts where dissolution is not requiredTrade-off Will not dissolve usefully in aqueous formats, which is why the salts exist
DGLLicorice extract with the glycyrrhizin removed, leaving flavonoids and polysaccharidesFits Formulas wanting licorice constituents without the mineralocorticoid effectTrade-off It is not a form of this ingredient at all, it is licorice with this ingredient taken out, so it does nothing that depends on glycyrrhizin

FDA Disclaimer: These statements have not been evaluated by the Food and Drug Administration. This information is for educational purposes only and is not intended to diagnose, treat, cure, or prevent any disease. Consult your healthcare provider before starting any supplement regimen.